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Copper octacarboxyphthalocyanine as sensitizer of graphitic carbon nitride for efficient dye degradation under visible light irradiation,
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Discipline: Chimie
Auteur(s): Seydou Ouedraogo , Bilel Choucheneb, , Christophe Desmarets , Thomas Gries , Lavinia Balane , René Fournet , Ghouti Medjahdi , Karifa Bayo , Raphaël Schneiderb
Auteur(s) tagués: BAYO Karifa
Renseignée par : BAYO Karifa
Résumé

In this paper, copper octacarboxyphthalocyanine (CuPc) was demonstrated to be an efficient photosensitizer of
graphitic carbon nitride (g-CN) for the degradation of dyes like Orange II or Methylene Blue under visible light
irradiation. UV–vis absorption, photoluminescence and photocurrent measurements demonstrate that CuPc not
only allows to extend the absorption to wavelengths up to 1000 nm but also enhances the charge-transfer efficiency. The high photocatalytic efficiency of CuPc/g-CN nanohybrids originates from the strong association
between the carboxylic acid groups of CuPc with g-CN which favor the transfer of photo-excited electrons from
CuPc to g-CN. The CuPc/g-CN catalyst is stable, can be reused up to five times without significant loss of activity
and is therefore of high potential for photocatalytic applications like wastewater treatment or hydrogen production under visible or near-infrared irradiation.

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