Reductive and oxidative combustion of polyethylene bags: Characterization of carbonaceous and nitrogenous species,
Auteur(s): Salifou K. Ouiminga, Thomas Rogaume, Tizane Daho, Arsène H. Yonli, Jean Koulidiati.
Auteur(s) tagués: Tizane DAHO ;
Résumé

This study aims to experimentally characterize the gaseous carbonaceous and nitrogenous species from
the reductive and oxidant combustion of polyethylene plastic bags. The experimental device used is the
tubular furnace, coupled to two gas analyzers: a Fourier transform infrared analyzer (FTIR) and a non
dispersive infrared analyzer (NDIR). The gaseous products analyzed are: CO, CO2, CH4, C3H8, C2H4, C2H2,
C6H6, HCN, N2O, NO, NO2 and NH3. The experiments were conducted at temperatures ranging from 800
to 1000 ◦C. The results obtained allow us to note that carbonaceous compounds are mainly emitted as
carbon oxides (CO and CO2) whether you are reductive combustion or oxidative combustion.
In addition:
- Under reductive conditions, combustion is controlled by oxygen. The hydrocarbon most active in the
formation of carbon monoxide is ethylene (C2H4) and to a lesser extent, from 900 ◦C, acetylene (C2H2).
The extents we have made show that ammonia seem to be emitted during combustion with 10% of
oxygen.
- In an oxidative environment, there is production of C6H6 in substantial quantities, which partly explains
the presence of soot and tar in the smoke exhaust ducts. The C2H4, CH4 and C2H2 are hydrocarbons most
active in the formation of CO and CO2. Increasing of concentration of local oxygen from 10 to 21% for the
combustion of plastic bags, favors an increase in efficiency of carbon conversion about 30%. About 99%
of the carbon of the fuel is found to be converted to carbon oxides or hydrocarbons. Nitrogen monoxide
(NO) is the major component among the gases measured with a conversion rate of nitrogen about 20%,
three times larger than that obtained during the reductive combustion of plastic bags with 10% oxygen

Mots-clés

Combustion Polyethylene Carbon Nitrogen

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